Are you trying to charge a lithium primary? That seems... unwise.
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Yes, this looks like a dual-chemistry slot charger that handles both NiMH and 3.6/3.7V Li-ion, which would charge each battery independently.
The battery in the third slot looks to be an Energizer L91 lithium-iron-disulfide primary battery. Those are not rechargeable, and attempting to charge one may cause it to explode.